共 22 条
Photoinduced oxygen-catalyzed RAFT polymerization using heterogeneous bionic enzymes
被引：2
|作者：
Yang, Hongjie
[1
]
Lu, Zhen
[2
,3
]
Fu, Xiaoling
[1
]
Li, Qiuyu
[1
]
Zhao, Yulai
[1
,2
,4
]
Xiao, Longqiang
[1
,2
,4
]
Hou, Linxi
[1
,2
,4
]
机构：
[1] Fuzhou Univ, Sch Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
[2] Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
[3] Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
[4] Fuzhou Univ, Fujian Key Lab Adv Mfg Technol Specialty Chem, Fuzhou 350116, Peoples R China
基金：
中国国家自然科学基金;
关键词：
RADICAL POLYMERIZATION;
NANOPARTICLES;
POLYMERS;
G-C3N4;
D O I：
10.1039/d2py00748g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ;
080501 ;
081704 ;
摘要：
Employing aerobic polymerization approaches is a feasible strategy to fundamentally address the phenomenon of oxygen blocked polymerization. A reversible addition-fragmentation chain transfer (RAFT) polymerization system (COF/H2O/O-2) using a photobionic enzyme was successfully constructed, in which a TFPPy-azine-COF serves as an enzyme-like workstation, oxygen and H2O are substrates, and light is an externally tunable stimulus to generate hydroxyl radicals for catalysing the RAFT polymerization. Molecularly diverse COFs provide a well-documented heterogeneous platform for the design and development of recyclable oxygen-catalyzed RAFT polymerization systems.
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页码：4776 / 4781
页数：6
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