Palladium-catalyzed cross-coupling reactions of in situ generated allylindium reagents with aryl halides

被引：100
|
作者：
Lee, PH [1 ]
Sung, SY [1 ]
Lee, K [1 ]
机构：
[1] Kangwon Natl Univ, Dept Chem, Chunchon 200701, South Korea
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 20期
关键词：
D O I：
10.1021/ol016532h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
GRAPHICS In situ generated allylindium reagents from the reaction of 1 equiv of indium with 1.5 equiv of allyl halides could be effective cross-coupling partners in palladium-catalyzed cross-coupling reactions to aryl halides. The best results were obtained with 2% Pd(2)dba(3)CHCl(3) and 16% Ph3P in the presence of 3 equiv of LiCl in DMF at 100 degreesC.
引用
收藏
页码：3201 / 3204
页数：4
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