Visible-light-induced, catalyst and additive-free cycloaddition of vinylcyclopropanes: access to sulfur-containing seven-membered heterocycles

被引：12

作者：

Huang, Xiaozhou ^{[1
]}

Wang, Rui ^{[1
]}

Zhou, Cen ^{[2
]}

Gao, Rong ^{[1
]}

Zhang, Haowen ^{[1
]}

Zheng, Ying ^{[1
]}

Zhang, Xiao ^{[1
]}

机构：

[1] Fujian Normal Univ, Fujian Key Lab Polymer Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Coll Chem & Mat Sci, 8 Shangsan Lu, Fuzhou 350007, Peoples R China

[2] Minjiang Univ, Ocean Coll, Fujian Engn & Res Ctr New Chinese Lacquer Mat, Fuzhou 350108, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 19期

关键词：

DEAROMATIVE 3+2 CYCLOADDITION; THIYL-RADICAL CATALYST; VINYL CYCLOPROPANES; DERIVATIVES; FUNCTIONALIZATION; VINYLAZIRIDINES; 3-NITROINDOLES; CYCLIZATION; POTENT; 1ST;

D O I：

10.1039/d1qo01007g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here we describe a visible-light-induced, catalyst and additive-free approach for the [5 + 2] cycloadditions of vinylcyclopropanes (VCPs) with thioparabanates. This operationally simple strategy provides straightforward and atom-economic access to functionalized sulfur-containing seven-membered heterocycles, which bear two contiguous fully substituted stereogenic centers under mild reaction conditions.

引用

页码：5454 / 5459

页数：6