Synthesis of novel L-proline derived macrocyclic dioxopolyamines of C2 symmetry

被引:3
|
作者
Yang, XM [1 ]
Li, BH [1 ]
Fu, EQ [1 ]
机构
[1] Wuhan Univ, Dept Chem, Wuhan, Peoples R China
基金
中国国家自然科学基金;
关键词
chiral macrocyclic dioxopolyamines; synthesis; L-proline; C-2; symmetry;
D O I
10.1081/SCC-200048458
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A short and convenient synthesis for four novel chiral L-proline derived macrocyclic dioxopolyamines of C-2 symmetry, by condensation of appropriate diester intermediates and polyamines, is reported. These macrocyclic dioxopolyamines may be applied as chiral solvating agents for enantiomeric recognition, and the work also provided a simple and convenient way for the synthesis of the diester intermediates.
引用
收藏
页码:271 / 278
页数:8
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