(R,RFc,SRu)-Chlorido(η6-p-cymene){1-[1-(diphenylphosphanyl)ethyl]-2-[2(diphenylphosphanyl)phenyl]ferrocene-κ2P,P′}ruthenium(II)hexafluoridophosphate

被引：1
|
作者：
Schuecker, Raffael [2 ]
Weissensteiner, Walter [2 ]
Mereiter, Kurt [1 ]
机构：
[1] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria
[2] Univ Vienna, Inst Organ Chem, A-1090 Vienna, Austria
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
LIGANDS; COMPLEXES;
D O I：
10.1107/S1600536811036506
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [FeRuCl-(C5H5)(C10H14)(C37H31P2)]PF6, contains two independent, geometrically similar Ru-II complexes of a chiral ferrocenyldiphosphane with piano-stool coordination through the eta(6)-bound p-cymene ligand, two chelating phosphorus donor atoms, and an exo-oriented chloride ion. The mean bond lengths of the two Ru complexes are Ru-C = 2.276 angstrom, Ru-P = 2.3816 angstrom, and Ru-Cl = 2.3924 angstrom. Both chloride ligands form only intramolecular C-H center dot center dot center dot Cl interactions. Seven weak intermolecular C-H center dot center dot center dot F interactions involving mainly arene H atoms consolidate the crystal packing, which reveals an approximate c/2 pseudo-translation relating the two independent Ru complex molecules.
引用
收藏
页码：M1379 / U775
页数：40
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