A phosphine-catalyzed [3+6] annulation reaction of modified allylic compounds and tropone

被引：182
|
作者：
Du, YH [1 ]
Feng, JQ [1 ]
Lu, XY [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 10期
关键词：
D O I：
10.1021/ol050443d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel phosphine-catalyzed reaction of modified allylic compounds, including acetates, bromides, chlorides, or tert-butyl carbonates derived from the Morita-Baylis-Hillman (MBH) reaction with tropone to yield [3+6] annulation products in excellent yields was developed. It offers a simple and convenient method for constructing bridged nine-membered carbocycles.
引用
收藏
页码：1987 / 1989
页数：3
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