Palladium Containing Catalysts Based on Hypercrosslinked Polystyrene for Selective Hydrogenation of Acetylene Alcohols

被引：34

作者：

Sulman, Esfir M. ^{[1
]}

Nikoshvili, Linda Zh. ^{[1
]}

Matveeva, Valentina G. ^{[1
]}

Tyamina, Irina Yu. ^{[1
]}

Sidorov, Alexander I. ^{[1
]}

Bykov, Alexey V. ^{[1
]}

Demidenko, Galina N. ^{[1
]}

Stein, Barry D. ^{[2
]}

Bronstein, Lyudmila M. ^{[3
]}

机构：

[1] Tver Tech Univ, Tver 170026, Russia

[2] Indiana Univ, Dept Biol, Bloomington, IN 47405 USA

[3] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

TOPICS IN CATALYSIS | 2012年 / 55卷 / 7-10期

关键词：

Nanocatalysis; Hypercrosslinked polystyrene; Palladium nanoparticles; Selective hydrogenation; CROSS-LINKED POLYSTYRENE; NANOPARTICLES; OXIDATION;

D O I：

10.1007/s11244-012-9810-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper reports palladium nanoparticle formation and stabilization by hypercrosslinked polystyrene and the catalytic properties of the nanocomposites obtained. The nanocomposites were characterized using low-temperature nitrogen physisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The inorganic nanoparticle size was found to depend on the Na2PdCl4 loading with the smallest nanoparticles formed at 0.1 wt% of Pd. The nanocomposites synthesized showed high activity [up to 27 mol/(mol Pd s)] and selectivity (up to 98.5 % at 100 % conversion) in selective hydrogenation of acetylene alcohols.

引用

页码：492 / 497

页数：6

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