SYNTHESIS OF HYDROXYMETHYLFURFURAL FROM SUCROSE USING BRONSTED-LEWIS ACIDIC IONIC LIQUID

被引：7
|
作者：
Yao, Lin [1 ]
Liu, Shiwei [1 ]
Li, Lu [1 ]
Yu, Shitao [1 ]
Liu, Fusheng [1 ]
Song, Zhanqian [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2016年 / 30卷 / 02期
关键词：
Acidic ionic liquid; Sucrose; 5-Hydroxymethylfurfural; Catalysis; CATALYST; FRUCTOSE; DEHYDRATION; CONVERSION; WATER;
D O I：
10.4314/bcse.v30i2.12
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of 5-hydroxymethylfurfural (HMF) from sucrose was investigated in the presence of the Bronsted-Lewis acidic ionic liquids (ILs). It was concluded that IL 1-(3-sulfonic acid)-propyl-3-methylimidazole chlorochrominate [HO3S-(CH2)(3)-mim] Cl-CrCl3 (molar fraction of CrCl3 x = 0.55) had a good catalytic performance with 78.8% yield of HMF. The acid type of IL played a significant role in the reaction. Lewis acid site acted more effectively than its Bronsted counterpart and a synergetic effect of Bronsted and Lewis acid sites enhanced the IL catalytic performance. The reusability of IL was good.
引用
收藏
页码：283 / 288
页数：6
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