SYNTHESIS OF HYDROXYMETHYLFURFURAL FROM SUCROSE USING BRONSTED-LEWIS ACIDIC IONIC LIQUID

被引：7
|
作者：
Yao, Lin [1 ]
Liu, Shiwei [1 ]
Li, Lu [1 ]
Yu, Shitao [1 ]
Liu, Fusheng [1 ]
Song, Zhanqian [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2016年 / 30卷 / 02期
关键词：
Acidic ionic liquid; Sucrose; 5-Hydroxymethylfurfural; Catalysis; CATALYST; FRUCTOSE; DEHYDRATION; CONVERSION; WATER;
D O I：
10.4314/bcse.v30i2.12
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of 5-hydroxymethylfurfural (HMF) from sucrose was investigated in the presence of the Bronsted-Lewis acidic ionic liquids (ILs). It was concluded that IL 1-(3-sulfonic acid)-propyl-3-methylimidazole chlorochrominate [HO3S-(CH2)(3)-mim] Cl-CrCl3 (molar fraction of CrCl3 x = 0.55) had a good catalytic performance with 78.8% yield of HMF. The acid type of IL played a significant role in the reaction. Lewis acid site acted more effectively than its Bronsted counterpart and a synergetic effect of Bronsted and Lewis acid sites enhanced the IL catalytic performance. The reusability of IL was good.
引用
收藏
页码：283 / 288
页数：6
相关论文
共 50 条
  • [1] Catalytic Production of Hydroxymethylfurfural from Fructose Using Bronsted-Lewis Acidic Ionic Liquid
    Liu, Shi-Wei
    Kong, Shan-Shan
    Li, Lu
    Yu, Shi-Tao
    Liu, Fu-Sheng
    Xie, Cong-Xia
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2015, 37 (03): : 447 - 451
  • [2] Synthesis of Glycerol Triacetate Using a Bronsted-Lewis Acidic Ionic Liquid as the Catalyst
    Liu, Shiwei
    Wang, Aiting
    Liu, Zhiguo
    Li, Lu
    Yu, Shitao
    Xie, Congxia
    Liu, Fusheng
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2015, 92 (09) : 1253 - 1258
  • [3] Dimerization of rosin using Bronsted-Lewis acidic ionic liquid as catalyst
    Liu, Shiwei
    Xie, Congxia
    Yu, Shitao
    Liu, Fusheng
    CATALYSIS COMMUNICATIONS, 2008, 9 (10) : 2030 - 2034
  • [4] Synthesis of novel Bronsted-Lewis acidic ionic liquid catalysts and their catalytic activities in acetalization
    Yan Wei
    Chen Keke
    Zhang Xiaofang
    Kuang Yingying
    Tang Xiujuan
    Han Xiaoxiang
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 29 : 185 - 193
  • [5] A Bronsted-Lewis Acidic Ionic Liquid: Its Synthesis and Use as the Catalyst in Rosin Dimerization
    Liu Shiwei
    Xie Congxia
    Yu Shitao
    Xian Mo
    Liu Fusheng
    CHINESE JOURNAL OF CATALYSIS, 2009, 30 (05) : 401 - 406
  • [6] An efficient Bronsted-Lewis acidic ionic liquid catalyzed tetrahydropyranylation of alcohols
    Azizi, Najmedin
    Abdoli-Senejani, Masumeh
    Abbasi, Faezeh
    TETRAHEDRON LETTERS, 2016, 57 (45) : 5009 - 5011
  • [7] Bronsted-Lewis acidic ionic liquid for the "one-pot" synthesis of biodiesel from waste oil
    Liu, Shiwei
    Wang, Zhiping
    Li, Kesheng
    Li, Lu
    Yu, Shitao
    Liu, Fusheng
    Song, Zhanqian
    JOURNAL OF RENEWABLE AND SUSTAINABLE ENERGY, 2013, 5 (02)
  • [8] Direct conversion of chitosan to 5-hydroxymethylfurfural in water using Bronsted-Lewis acidic ionic liquids as catalysts
    Jiang, Yi
    Zang, Hongjun
    Han, Sheng
    Yan, Bing
    Yu, Songbai
    Cheng, Bowen
    RSC ADVANCES, 2016, 6 (105) : 103774 - 103781
  • [9] Dimerization of fatty acid methyl ester using Bronsted-Lewis acidic ionic liquid as catalyst
    Liu, Shiwei
    Zhou, Hongxia
    Yu, Shitao
    Xie, Congxia
    Liu, Fusheng
    Song, Zhanqian
    CHEMICAL ENGINEERING JOURNAL, 2011, 174 (01) : 396 - 399
  • [10] Alkylation of isobutane/isobutene using Bronsted-Lewis acidic ionic liquids as catalysts
    Liu, Shiwei
    Chen, Chuangang
    Yu, Fengli
    Li, Lu
    Liu, Zhiguo
    Yu, Shitao
    Xie, Congxia
    Liu, Fusheng
    FUEL, 2015, 159 : 803 - 809
12345