Mesoporous aluminophosphate thin films with cubic pore arrangement

被引：15
|
作者：
Mazaj, A. [3 ]
Costacurta, S. [4 ]
Logar, N. Zabukovec [3 ]
Mali, G. [3 ]
Tusar, N. Novak [3 ]
Innocenzi, P. [4 ]
Malfatti, L. [4 ]
Thibault-Starzyk, F. [5 ]
Amenitsch, H. [6 ]
Kaucic, V. [3 ]
Soler-Illia, G. J. A. A. [1 ,2 ]
机构：
[1] Comis Nacl Energia Atom, RA-1429 Buenos Aires, DF, Argentina
[2] Consejo Nacl Invest Cient & Tecn, RA-1033 Buenos Aires, DF, Argentina
[3] Natl Inst Chem, Ljubljana 1000, Slovenia
[4] Univ Sassari, Lab Sci Mat & Nanotecnol, Dipartimento Architettura & Pianificaz, INSTM, I-07041 Alghero, SS, Italy
[5] Inst Sci Mat & Rayonnement, CNRS, Catalyse & Spectrochim Lab, F-14050 Caen, France
[6] Austrian Acad Sci, Inst Biophys & Nanosyst Res, A-8042 Graz, Austria
来源：
LANGMUIR | 2008年 / 24卷 / 12期
关键词：
D O I：
10.1021/la7035746
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mesoporous aluminophosphate thin films with 3D cubic (Win) pore arrangement were synthesized for the first time. Thin films were templated with block copolymer nonionic templates Pluronic F127 and F108 and deposited on a glass substrate by dip-coating. In situ SAXS investigations show the formation of a highly ordered mesostructure upon the dip-coating process, which remains stable up to at least 670 K. A cubic mesostructure was observed also by TEM. Template removal process was monitored by TG and FT-IR. A transition from an amorphous aluminophosphate gel to a well-defined aluminophosphate framework was observed by MAS NMR.
引用
收藏
页码：6220 / 6225
页数：6
相关论文
共 50 条
  • [41] Mesoporous titania thin films with pseudo-cubic structure: Synthetic studies and applications to nanomembranes and nanotemplates
    Lee, UH
    Lee, H
    Wen, S
    Mho, SI
    Kwon, YU
    MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 88 (1-3) : 48 - 55
  • [42] Cubic erbium trihydride thin films
    Adams, D. P.
    Rodriguez, M. A.
    Romero, J. A.
    Kotula, P. G.
    Banks, J.
    THIN SOLID FILMS, 2012, 520 (19) : 6145 - 6152
  • [43] Formation of continuous cubic mesoporous films by spin casting
    Honma, I
    Zhou, HS
    Kundu, D
    ORGANIC/INORGANIC HYBRID MATERIALS, 1998, 519 : 109 - 115
  • [44] Controlling drug delivery kinetics from mesoporous titania thin films by pore size and surface energy
    Karlsson, Johan
    Atefyekta, Saba
    Andersson, Martin
    INTERNATIONAL JOURNAL OF NANOMEDICINE, 2015, 10 : 4425 - 4436
  • [45] Pore structure determination of mesoporous SiO2 thin films by slow positron annihilation spectroscopy
    Wang Qiao-Zhan
    Yu Run-Sheng
    Qin Xiu-Bo
    Li Yu-Xiao
    Wang Bao-Yi
    Jia Quan-jie
    ACTA PHYSICA SINICA, 2009, 58 (12) : 8478 - 8483
  • [46] Mesoporous Zirconia Thin Films with Three-Dimensional Pore Structures and Their Application to Electrochemical Glucose Detection
    Ko, Young-Seon
    Kwon, Young-Uk
    ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (09) : 3599 - 3606
  • [47] Preparation of amino-functionalized mesoporous silica thin films with highly ordered large pore structures
    Zhang, Xueao
    Wang, Jianfang
    Wu, Wenjian
    Liu, Changli
    Qian, Siwen
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2007, 43 (03) : 305 - 311
  • [48] Preparation of amino-functionalized mesoporous silica thin films with highly ordered large pore structures
    Xueao Zhang
    Jianfang Wang
    Wenjian Wu
    Changli Liu
    Siwen Qian
    Journal of Sol-Gel Science and Technology, 2007, 43 : 305 - 311
  • [49] Role of pore morphology in positronium diffusion in mesoporous silica thin films and in positronium emission from the surfaces
    He, Chunqing
    Wang, Shaojie
    Kobayashi, Yoshinori
    Ohdaira, Toshiyuki
    Suzuki, Ryoichi
    PHYSICAL REVIEW B, 2012, 86 (07)
  • [50] The Use of Different Templates for the Synthesis of Reproducible Mesoporous Titania Thin Films and Small Pore Ultrafiltration Membranes
    Herregods, Sebastiaan Johan Frans
    Wyns, Kenny
    Buekenhoudt, Anita
    Meynen, Vera
    ADVANCED ENGINEERING MATERIALS, 2019, 21 (11)
12345