Synthesis and studies of photochromic properties of spirobenzopyran carboxy derivatives and their model compounds as potential markers

被引:7
|
作者
Laptev, A. V. [1 ]
Lukin, A. Yu [1 ]
Belikov, N. E. [2 ]
Zvezdin, K. V. [1 ]
Demina, O. V. [2 ]
Barachevsky, V. A. [3 ]
Varfolomeev, S. D. [2 ]
Khodonov, A. A. [1 ,2 ]
Shvets, V. I. [1 ]
机构
[1] MV Lomonosov Moscow State Univ Fine Chem Technol, Moscow 119571, Russia
[2] Russian Acad Sci, NM Emanuel Inst Biochem Phys, Moscow 119991, Russia
[3] Russian Acad Sci, Ctr Photochem, Moscow 119421, Russia
基金
俄罗斯基础研究基金会;
关键词
spiropyran; Horner-Emmons olefination; Knoevenagel condensation; photochromic markers; AMPEROMETRIC TRANSDUCTION; HELICAL STRUCTURES; GLUCOSE-OXIDASE; SHORT PEPTIDES; SPIROPYRAN; BINDING;
D O I
10.1007/s11172-014-0695-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A number of photochromic markers, viz., spirobenzopyrans containing one or two active carboxy groups attached directly or through a spacer, as well as their model derivatives, were synthesized. The obtained compounds were characterized by instrumental methods of analysis. Spectrokinetic methods were used to study the behavior of the spirobenzopyran markers and the model derivatives in solutions in EtOH and toluene.
引用
收藏
页码:2026 / 2035
页数:10
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