Sulfated steroid compounds from the starfish Aphelasterias japonica of the Kuril population

被引：22
|
作者：
Kicha, AA [1 ]
Ivanchina, NV [1 ]
Kalinovsky, AI [1 ]
Dmitrenok, PS [1 ]
Stonik, VA [1 ]
机构：
[1] Russian Acad Sci, Pacific Inst Bioorgan Chem, Vladivostok 690022, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 04期
关键词：
starfish Aphelasterias japonica; glycosides; polyhydroxysteroid; asterosaponin aglycons;
D O I：
10.1023/A:1011337617808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four sulfated steroid compounds were isolated from the Kuril population of the starfish Aphelasterias japonica. The structure of a new glycoside, aphelasteroside D, was elucidated as (24R)-29-O-[2-O-sulfo-beta -D-glucopyranosyl]-24-ethyl-5 alpha -cholestane-3 beta ,5,6 beta ,8 beta ,15 alpha ,29-hexol sodium salt. Other three substances were identified as the known pycnopodioside C, 3-O-sulfo-24,25-dihydromarthasterone, and 3-O-sulfothornasterol A, the latter compound being isolated as a tyrammonium salt for the first time.
引用
收藏
页码：724 / 727
页数：4
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