Conversion of guaiacol as lignin model component using acid-treated, multi-walled carbon nanotubes supported Ru-MnO bimetallic catalysts

被引：12
|
作者：
Long, Wei [1 ]
Liu, Pingle [1 ,2 ]
Xiong, Wei [1 ,2 ]
Hao, Fang [1 ,2 ]
Luo, He'an [1 ,2 ]
机构：
[1] Xiangtan Univ, Coll Chem Engn, Xian 411105, Shaanxi, Peoples R China
[2] Xiangtan Univ, Natl & Local United Engn Res Ctr Chem Proc Simula, Xiangtan 411105, Hunan, Peoples R China
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2020年 / 98卷 / 02期
关键词：
heterogeneous catalysis; bimetallic catalysts; guaiacol; hydrodeoxygenation; VAPOR-PHASE HYDRODEOXYGENATION; MOLYBDENUM NITRIDE CATALYSTS; BIO-OIL PRODUCTION; FE CATALYSTS; PYROLYSIS; HYDROGENATION; NI; BIOMASS; SILICA; NANOPARTICLES;
D O I：
10.1139/cjc-2019-0261
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acid-treated, multi-walled carbon nanotube (AMWCNT) supported Ru and MnO bimetallic catalysts were prepared for liquid phase hydrodeoxygenation of guaiacol. The physicochemical properties of the prepared catalysts were characterized by FTIR, XRD, NH3-TPD, CO2-TPD, TEM, and XPS. MnO species were loaded on the inner surface of carbon nanotubes and were helpful for Ru particle dispersion. The 6%Ru-8%MnO/AMWCNTs with smaller Ru particle size, better dispersion, and more basic sites gave the best catalytic performance of 99.38% conversion of guaiacol and 85.84% selectivity to cyclohexanol. The effects of reaction conditions on liquid phase guaiacol hydrodeoxygenation were discussed and a possible reaction path was proposed.
引用
收藏
页码：57 / 65
页数：9
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