One-pot reductive amination of acetals with aromatic amines using decaborane (B10H14) in methanol

被引：9

作者：

Park, ES ^{[1
]}

Lee, JH ^{[1
]}

Kim, SJ ^{[1
]}

Yoon, CM ^{[1
]}

机构：

[1] Korea Univ, Grad Sch Biotechnol, Seoul 136701, South Korea

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 19期

关键词：

one-pot reaction; reductive amination; decaborane; acetals; ketals;

D O I：

10.1081/SCC-120023997

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldehyde acetals and ketone ketals were reductively aminated in one pot with aromatic amines to give the corresponding amines in methanol or aqueous methanol in good to high yields. This direct method might be important because acetals and ketals are used as a popular protecting group for aldehyde and ketones. The advantage of our method is effective even in an aqueous solution and in the application to selective reaction.

引用

页码：3387 / 3396

页数：10

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