Oxo/imido heterometathesis: From molecular stoichiometric studies to well-defined heterogeneous catalysts

被引：9
|
作者：
Zhizhko, Pavel A. [1 ]
Bushkov, Nikolai S. [1 ,2 ]
Pichugov, Andrey, V [1 ,3 ]
Zarubin, Dmitry N. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Vorobevy Gory 1, Moscow 119991, Russia
[3] D Mendeleev Univ Chem Technol Russia, Higher Chem Coll, Miusskaya Sq 9, Moscow 125047, Russia
来源：
COORDINATION CHEMISTRY REVIEWS | 2021年 / 448卷
基金：
俄罗斯科学基金会;
关键词：
Imido; Oxo; Metathesis; Heterometathesis; Cycloaddition; Surface Organometallic Chemistry; SURFACE ORGANOMETALLIC CHEMISTRY; TRANSITION-METAL-COMPLEXES; TITANIUM IMIDO COMPLEXES; SOLID-STATE NMR; OLEFIN-METATHESIS CATALYSTS; 2+2 CYCLOADDITION REACTIONS; CARBON-DIOXIDE ACTIVATION; HYDROGEN BOND ACTIVATION; NITROGEN-ATOM EXCHANGE; C-H ACTIVATION;
D O I：
10.1016/j.ccr.2021.214112
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxo/imido heterometathesis is a class of reactions that interconvert terminal transition metal oxo and imido complexes via [2 + 2] cycloaddition/cycloreversion with heteroolefins and heterocumulenes containing oxo and imino groups. In this review we summarize the literature examples of stoichiometric oxo/imido heterometathesis reactions of imido complexes with different oxo substrates and discuss the current progress in the development of catalytic oxo/imido heterometathesis. In particular, we show how application of Surface Organometallic Chemistry approach allows preparation of highly efficient oxo/imido heterometathesis catalysts based on well-defined silica-supported early transition metal oxo and imido complexes. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数：41
相关论文
共 50 条
  • [21] A Well-Defined Terminal Vanadium(III) Oxo Complex
    King, Amanda E.
    Nippe, Michael
    Atanasov, Mihail
    Chantarojsiri, Teera
    Wray, Curtis A.
    Bill, Eckhard
    Neese, Frank
    Long, Jeffrey R.
    Chang, Christopher J.
    INORGANIC CHEMISTRY, 2014, 53 (21) : 11388 - 11395
  • [22] WELL-DEFINED SUPPORTED METAL-CATALYSTS PREPARED FROM MOLECULAR-METAL CLUSTERS
    BUDGE, J
    BARTH, R
    SCOTT, JP
    LIETO, J
    WOLF, M
    GATES, BC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 183 (MAR): : 10 - PETR
  • [23] Colloidally Prepared Nanoparticles for the Synthesis of Structurally Well-Defined and Highly Active Heterogeneous Catalysts
    Juergens, Birte
    Borchert, Holger
    Ahrenstorf, Kirsten
    Sonstroem, Patrick
    Pretorius, Angelika
    Schowalter, Marco
    Gries, Katharina
    Zielasek, Volkmar
    Rosenauer, Andreas
    Weller, Horst
    Baeumer, Marcus
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) : 8946 - 8949
  • [24] Design of selective catalysts with well-defined shapes
    Lee, Ilkeun
    Delbecq, Francoise
    Zaera, Francisco
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [25] OLEFIN METATHESIS BY WELL-DEFINED RHENIUM CATALYSTS
    TOREKI, R
    SCHROCK, RR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 194 - INOR
  • [26] MOLECULAR CHEMISTRY AT WELL-DEFINED SURFACES
    HUBBARD, AT
    GUI, JY
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1991, 88 (7-8) : 1547 - 1590
  • [27] In-situ studies of catalytic reactions over well-defined model catalysts
    Zhou Q.
    Cai J.
    Wang W.
    Liu Z.
    Yang F.
    Catalysis, 2021, 33 : 380 - 416
  • [28] ATOMIC AND MOLECULAR SCATTERING FROM CRYSTALLOGRAPHICALLY WELL-DEFINED SURFACES
    MERRILL, RP
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1972, 9 (02): : 803 - &
  • [29] INOR 91-Silica support effects in well-defined heterogeneous molybdenum metathesis catalysts
    Nelson, Ryan C.
    Wixson, Laurel K.
    Scott, Susannah L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
  • [30] Well-Defined Palladium Nanoparticles Supported on Siliceous Mesocellular Foam as Heterogeneous Catalysts for the Oxidation of Water
    Verho, Oscar
    Akermark, Torbjorn
    Johnston, Eric V.
    Gustafson, Karl P. J.
    Tai, Cheuk-W.
    Svengren, Henrik
    Karkas, Markus D.
    Backvall, Jan-E.
    Akermark, Bjorn
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (15) : 5909 - 5915
12345