Photochemical synthesis and properties of axially chiral naphthylpyridines

被引：11
|
作者：
Wessig, Pablo [1 ]
Pick, Charlotte [1 ]
机构：
[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2011年 / 222卷 / 01期
关键词：
Photochemistry; Axial chirality; Photo-Dehydro-Diels-Alder reaction; Dynamic NMR; Dynamic HPLC; Molecular modeling; 2+2+2 CYCLOADDITION; THERMOCHEMISTRY; BENZANNULATION; COMPLEXES; HALIDES;
D O I：
10.1016/j.jphotochem.2011.06.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Five alkynyl pyridines were prepared and cyclized to naphthylpyridines as the main products in the course of a Photo-Dehydro-Diels-Alder reaction. Four of the final products are axially chiral and the determination of the rotational barrier by DFT calculations, dynamic NMR and H PLC experiments is demonstrated. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：263 / 265
页数：3
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