Synthesis and chiroptical properties of axially chiral, binaphthol-based oligomers

被引：29
|
作者：
Ng, MK [1 ]
Chow, HF [1 ]
Chan, TL [1 ]
Mak, TCW [1 ]
机构：
[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,NT,HONG KONG
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期
关键词：
binaphthol; optical active oligomers; optical activity;
D O I：
10.1016/0040-4039(96)00478-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active, axially chiral binaphthol-based oligomers 2 to 4 were synthesized via Hay's coupling from the monomer 1. These oligomers exhibited moderate optical rotation enhancement but the effect quickly reaches a plateau with the tetramer 4. (C) 1996 Elsevier Science Ltd
引用
收藏
页码：2979 / 2982
页数：4
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