Hydrogen cleavage by solid-phase frustrated Lewis pairs

被引：43
|
作者：
Xing, Jun-Yi [1 ]
Buffet, Jean-Charles [1 ]
Rees, Nicholas H. [1 ]
Norby, Peter [1 ]
O'Hare, Dermot [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, 12 Mansfield Rd, Oxford OX1 3TA, England
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 69期
关键词：
OLEFIN POLYMERIZATION; H-2; ACTIVATION; BORANE; SILICA; CO2; CHEMISTRY; CATALYSTS; METHANOL; STATE; SPECTROSCOPY;
D O I：
10.1039/c6cc04937k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the direct synthesis of a solid-phase frustrated Lewis pair (s-FLP) by combining a silica-supported Lewis acid ( SiOB(C6F5)(2), s-BCF) with a Lewis base (tri-tert-butylphosphine, (Bu3P)-Bu-t) to give [ SiOB(C6F5)(2)][(Bu3P)-Bu-t]. Reaction of this s-FLP with H-2 under mild conditions led to heterolytic H-H bond cleavage and the formation of [ SiOB(H)(C6F5)(2)][(Bu3PH)-Bu-t].
引用
收藏
页码：10478 / 10481
页数：4
相关论文
共 50 条
  • [41] Investigating Tetrel-Based Neutral Frustrated Lewis Pairs for Hydrogen Activation
    Sarkar, Pallavi
    Das, Shubhajit
    Pati, Swapan K.
    INORGANIC CHEMISTRY, 2021, 60 (20) : 15180 - 15189
  • [42] External stimulus controlled recombination of hydrogen in photochromic dithienylethene frustrated lewis pairs
    Fazl-i-Sattar
    Ahmed, Arsalan
    Ullah, Habib
    Ullah, Zakir
    Tariq, Muhammad
    Ayub, Khurshid
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (59) : 31141 - 31152
  • [43] Hydrogen activation enabled by the interfacial frustrated Lewis pairs on cobalt borate nanosheets
    Zhang, Sai
    Huang, Zheng-Qing
    Chen, Xiao
    Gan, Jie
    Duan, Xuezhi
    Yang, Bolun
    Chang, Chun-Ran
    Qu, Yongquan
    JOURNAL OF CATALYSIS, 2019, 372 : 142 - 150
  • [44] Stretching C-H bond in methane by solid frustrated Lewis pairs
    Zhao, Jiankang
    Yan, Han
    Zeng, Jie
    CHEM CATALYSIS, 2022, 2 (07): : 1521 - 1523
  • [45] Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds
    Mandal, Dipendu
    Chen, Ting
    Qu, Zheng-Wang
    Grimme, Stefan
    Stephan, Douglas W.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (37)
  • [46] Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs
    Gilbert, Thomas M.
    FRUSTRATED LEWIS PAIRS I: UNCOVERING AND UNDERSTANDING, 2013, 332 : 267 - 289
  • [47] Solid-phase synthesis of Lewis antigens.
    Seeberger, PH
    Andrade, RB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U115 - U115
  • [48] Frustrated Lewis pairs as ligands for organometallic catalysis
    Nichols, Brian R.
    Popp, Brian V.
    Bennett, C. Eugene
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [49] Nothing frustrating about "Frustrated Lewis pairs"
    Stephan, Douglas W.
    DALTON TRANSACTIONS, 2012, 41 (30) : 9015 - 9015
  • [50] Polymerization catalysis by classical and frustrated Lewis pairs
    Chen, Eugene
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
12345