[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II)

被引：1

作者：

Wang, Zhi-Wei ^{[1
]}

Liu, Ran ^{[1
]}

Liu, Hong-Yu ^{[1
]}

Wan, Chong-Qing ^{[1
]}

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

CRYSTAL-STRUCTURE;

D O I：

10.1107/S1600536810049664

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the mononuclear title complex, [Pt(C7H7)(2)(C8H12)], the Pt-II ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two pi-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship with a C-Pt-C bond angle of 88.54 (18)degrees and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)degrees. Each complex molecule links to four symmetry-related ones through intermolecular C-H center dot center dot center dot pi interactions, forming a layer almost parallel to the bc plane.

引用

页码：M37 / U485

页数：11

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