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Two heterometallic coordination polymers based on Sr(II) ion and dicarboxylate ligand
被引:5
|作者:
Chen, Yanmei
[1
]
Zou, Shuixiang
[1
]
Tang, Yumeng
[1
]
Hu, Hailiang
[2
]
机构:
[1] Huanggang Normal Univ, Coll Chem & Chem Engn, Hubei Key Lab Proc & Applicat Catalyt Mat, Huanggang 438000, Peoples R China
[2] Guizhou Minzu Univ, Sch Chinese Pharm, Sch Chem Engn, Guiyang 550025, Guizhou, Peoples R China
来源:
关键词:
Heterometallic coordination polymers;
Luminescent properties;
Alkaline earth metal complexes;
Luminescence lifetimes;
Zn/Cd complexes;
METAL-ORGANIC FRAMEWORKS;
M-II M;
LUMINESCENT PROPERTIES;
CRYSTAL-STRUCTURES;
SR-II-LN(III) LN;
SERIES;
ZN;
NI;
CO;
CU;
D O I:
10.1016/j.poly.2018.11.011
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Two new heterometallic coordination polymers(CPs) [ZnSr(pydc)(2)(H2O)(6)](n)center dot 2nH(2)O (1) and [CdSr (Pydc)(2)(H2O)(2)](n) (2) (H(2)pydc = pyridine-2,4-dicarboxylic acid) based on Sr-II ion and pyridine-2,4-dicarboxylate (H(2)pydc) have been solvothermally synthesized and characterized. Single crystal structure analysis shows that complex 1 is a pts topology based on Sr-Zn, and complex 2 is qtz topology based on Sr-Cd. Complex 2 was the first reported Sr-Cd complex being supported by pyridine-2,4-dicarboxylic acid. The solid state luminescent properties of 1 and 2 were studied. (C) 2018 Elsevier Ltd. All rights reserved.
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页码:18 / 23
页数:6
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