Application of modified iron-containing catalysts and preliminary ozonization of coal from the Shubarkol deposit to the hydrogenation of this coal

被引:4
|
作者
Kairbekov, Zh. K. [1 ]
Maloletnev, A. S. [2 ]
Dzheldybaeva, I. M. [3 ]
Sabitova, A. N. [3 ]
Ermoldina, E. T. [3 ]
机构
[1] Res Inst New Chem Technol & Mat, Alma Ata, Kazakhstan
[2] Moscow State Min Inst NITU MISiS, Moscow, Russia
[3] Al Farabi State Univ Kazakhstan, Alma Ata, Kazakhstan
关键词
Elemental sulfur - Higher yield - Iron containing catalysts - Kazakhstan - Liquid products;
D O I
10.3103/S0361521917060039
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of the hydrogenation processing of coal from the Shubarkol deposit in the presence of natural bauxites from the Turgai deposit in the Republic of Kazakhstan are reported. With the use of a sample of bauxite containing 23.7% Fe2O3 as a catalyst, a higher yield of liquid products (54.2%) was obtained, as compared with those on other bauxite samples (49.5-53.8%). It was established that the modification of catalysts containing iron with elemental sulfur additives (0.75-1.25%) makes it possible to increase the yield of liquid products to 62.3-67.3%. A positive role of the preliminary ozonization of coal, which makes it possible to increase the yield of total liquid products upon hydrogenation by 13.3% in comparison with the yield of liquid products obtained with the use of coal not treated with ozone, was demonstrated.
引用
收藏
页码:365 / 369
页数:5
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