Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water

被引：19

作者：

Zhang, Jin ^{[1
]}

Du, Jihong ^{[1
]}

Zhang, Chenyang ^{[1
]}

Liu, Kun ^{[1
]}

Yu, Feifei ^{[1
]}

Yuan, Yongkun ^{[2
]}

Duan, Baogen ^{[2
]}

Liu, Renhua ^{[1
,3
]}

机构：

[1] East China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

[2] Suzhou Yacoo Sci Co Ltd, Suzhou 215125, Jiangsu, Peoples R China

[3] Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China

来源：

ORGANIC LETTERS | 2022年 / 24卷 / 05期

关键词：

EXCHANGE-REACTION; METHYLARENES;

D O I：

10.1021/acs.orglett.1c04154

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here a palladium-catalyzed oxidation method for converting alkylarenes into the aromatic ketones or benzaldehydes with water as the only oxygen donor is reported. This C-H bond oxidation functionalization does not require other oxidants and hydrogen acceptors, and H-2 is the only byproduct. The oxygen atom introduced into the products is confirmed to be from water by the MS analysis on the product of the O-18-labeled water reaction.

引用

页码：1152 / 1157

页数：6

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