An easy access to aryl azides from aryl amines under neutral conditions

被引：55

作者：

Das, J ^{[1
]}

Patil, SN ^{[1
]}

Awasthi, R ^{[1
]}

Narasimhulu, CP ^{[1
]}

Trehan, S ^{[1
]}

机构：

[1] Dr Reddys Labs Ltd, Discovery Res, Hyderabad 500049, Andhra Pradesh, India

来源：

SYNTHESIS-STUTTGART | 2005年 / 11期

关键词：

amines; azides; anilines; diazo compounds; sodium azide;

D O I：

10.1055/s-2005-869974

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of substituted aryl amines were transformed into aryl azides using t-BuONO and moist NaN3 in t-BuOH in good to excellent yields. Smooth transformation was observed with anilines, having electron withdrawing and donating groups. Both acid- and base-sensitive groups survived the reaction conditions.

引用

页码：1801 / 1806

页数：6

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