The heat capacity and standard thermodynamic functions of Ni0.5Zr2(PO4)3 phosphate over the temperature range from T → 0 to 664 K

被引:9
|
作者
Pet'kov, V. I. [1 ]
Markin, A. V. [1 ]
Shchelokov, I. A. [1 ]
Sukhanov, M. V. [1 ]
Smirnova, N. N. [1 ]
机构
[1] Nizhnii Novgorod State Univ, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
Crystalline materials - Entropy - Fractal dimension - Phosphates - Polonium compounds - Specific heat - Zirconium compounds;
D O I
10.1134/S0036024407110027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The temperature dependence of the heat capacity of crystalline nickel zirconium phosphate C-p(circle) = f(T) was measured over the temperature range 6-664 K. The experimental data obtained were used to calculate the standard thermodynamic functions of Ni0.5Zr2(PO4)(3) from T -> 0 to 664 K. The standard entropy of phosphate formation from simple substances at 298.15 K was calculated from the absolute entropy of the compound. The data on the low-temperature heat capacity were used to determine the fractal dimension of Ni0.5Zr2(PO4)(3) over the temperature range 30-50 K. Conclusions concerning the heterodynamic characteristics of the structure of Ni0.5Zr2(PO4)(3) were drawn.
引用
收藏
页码:1728 / 1733
页数:6
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