Electronic structures and X-ray photoelectron spectra of TeIV halides with N,N′-diphenylguanidine

被引：6

作者：

Dotsenko, A. A. ^{[1
]}

Vovna, V. I. ^{[1
]}

Korochentsev, V. V. ^{[1
]}

Os'mushko, I. S. ^{[1
]}

Mirochnik, A. G. ^{[2
]}

Sedakova, T. V. ^{[2
]}

机构：

[1] Far East Fed Univ, 8 Ul Sukhanova, Vladivostok 690950, Russia

[2] Russian Acad Sci, Far East Branch, Inst Chem, 159 Prosp 100 Letiya Vladivostoka, Vladivostok 690022, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 10期

关键词：

X-ray photoelectron spectroscopy; density functional theory; electronic structure; tellurium hexahalides; PHASE-TRANSITIONS; CRYSTAL-STRUCTURE; LUMINESCENCE; COMPLEXES; ANTIMONY(III);

D O I：

10.1007/s11172-015-1168-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electronic structures of Te-IV hexahalides with N,N'-diphenylguanidine were studied by X-ray photoelectron spectroscopy and quantum chemistry. New information was obtained for the electronic structures of the complexes, the chemical bond nature for these compounds was established, and the bands of the X-ray photoelectron spectra in the valence band were identified.

引用

页码：2393 / 2399

页数：7

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