EPR studies of blends of polyaniline with poly(methyl methacrylate-co-glycidyl methacrylate iminodiacetic acid)

被引：11
|
作者：
Liu, HK
Shih, CC
Wang, GP
Wu, TR
Wu, KH
Chang, TC [1 ]
机构：
[1] NDU, Chung Cheng Inst Technol, Dept Appl Chem, Taoyuan 335, Taiwan
[2] Chung Shan Inst Sci & Technol, Chem Syst Res Div, Taoyuan 325, Taiwan
来源：
SYNTHETIC METALS | 2005年 / 151卷 / 03期
关键词：
PMGI; polyaniline; blends; EPR;
D O I：
10.1016/j.synthmet.2005.05.009
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel conductive blends of polyaniline (PANI) with poly(methyl methacrylate-co-glycidyl methacrylate iminodiacetic acid) (PANI-PMGI) was prepared by in situ dispersion polymerization. The PANI-PMGI blends were characterized by UV-vis, FTIR and electron paramagnetic resonance (EPR) spectra. The structure of the PANI-PMGI blends was similar to emeraldine salt proved by UV-vis and FTIR. The value of Delta H-pp, lineshape, g factor, N-s and A/B ratio of blends were investigated by EPR. The results of EPR indicated that the intermolecular interaction between PANI and PMGI was dependent on the content of PANI and temperature. (C) 2005 Elsevier B.V. All rights reserved.
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页码：256 / 260
页数：5
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