Catalytic asymmetric metal carbene transformations

被引：28
|
作者：
Forbes, DC [1 ]
McMills, MC
机构：
[1] Univ S Alabama, Dept Chem, Mobile, AL 36608 USA
[2] Ohio Univ, Dept Chem & Biochem, Athens, OH 45701 USA
来源：
CURRENT ORGANIC CHEMISTRY | 2001年 / 5卷 / 11期
关键词：
D O I：
10.2174/1385272013374815
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The application of stabilized metal carbenes as reactive intermediates in synthesis has greatly expanded because of the wide array of structures that are available from these reactions. In order to expand the usefulness of these reactions, several investigators have focused on the development of chiral catalysts that cab effect asymmetric carbene reactions. This review will cover the development and application of these catalysts.
引用
收藏
页码：1091 / 1105
页数：15
相关论文
共 50 条
  • [41] Metal Hybrid Nanoparticles for Catalytic Organic and Photochemical Transformations
    Song, Hyunjoon
    ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (03) : 491 - 499
  • [42] Synthesis of atropisomers via transition-metal-catalyzed enantioselective carbene transformations
    Pan, Chongqing
    Gu, Zhenhua
    TRENDS IN CHEMISTRY, 2023, 5 (09): : 684 - 696
  • [43] Organic transformations catalyzed by N-heterocyclic carbene-metal complexes
    Li, LT
    Ma, SM
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2001, 21 (01) : 75 - 81
  • [44] Recent quinone diazide based transformations via metal-carbene formation
    Bera, Satabdi
    Sarkar, Souradip
    Samanta, Rajarshi
    NEW JOURNAL OF CHEMISTRY, 2021, 45 (23) : 10135 - 10149
  • [45] Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations
    Qi, Xiaotian
    Lan, Yu
    ACCOUNTS OF CHEMICAL RESEARCH, 2021, 54 (14) : 2905 - 2915
  • [46] Direct Catalytic Asymmetric Addition of Alkylnitriles to Aldehydes with Designed Nickel-Carbene Complexes
    Saito, Akira
    Adachi, Shinya
    Kumagai, Naoya
    Shibasaki, Masakatsu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (16) : 8739 - 8743
  • [47] Catalytic Asymmetric Carbene Transfer Reactions of Diazo Oxime Ethers with Olefins and Their Synthetic Applications
    Da Ho, Linh
    Otog, Nansalmaa
    Fujisawa, Ikuhide
    Iwasa, Seiji
    ORGANIC LETTERS, 2019, 21 (18) : 7470 - 7474
  • [48] Enantioselective α-Boryl Carbene Transformations
    Huang, Ming-Yao
    Zhao, Jia-Bao
    Zhang, Cheng-Da
    Zhou, Yuan-Jun
    Lu, Zhan-Sheng
    Zhu, Shou-Fei
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (14) : 9871 - 9879
  • [49] Catalytic Asymmetric Intermolecular Cyclopropanation of a Ketone Carbene Precursor by a Ruthenium(II)-Pheox Complex
    Le Thi Loan Chi
    Suharto, Agus
    Ho Linh Da
    Soda Chanthamath
    Shibatomi, Kazutaka
    Iwasa, Seiji
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (05) : 951 - 955
  • [50] Asymmetric transformations of acyloxyphenyl ketones by enzyme-metal multicatalysis
    Kim, MJ
    Choi, MY
    Han, MY
    Choi, YK
    Lee, JK
    Park, J
    JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (26): : 9481 - 9483
12345