Nucleophilic addition reactions of tricarbonyl [eta(5)-1-(phenylthio)cyclohexadienyl]iron(I) complex

被引：2

作者：

Chou, SSP

Hsu, CH

机构：

[1] Department of Chemistry, Fu Jen Catholic University

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1996年 / 43卷 / 04期

关键词：

iron complexes; dienes; nucleophilic addition reactions;

D O I：

10.1002/jccs.199600051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydride abstraction of tricarbonyl[eta(4)-1-(phenylthio)-1,3-cyclohexadiene]iron(0) complex 2 with Ph(3)C(+)PE(6)(-) regiospecifically provided the title compound 3 in excellent yield. Cationic complex 3 could react with a variety of nucleophiles in good yield. Hard nucleophiles prefer to attack at the C-l position, whereas soft and hindered nucleophiles favor attack at the C-5 position. Some synthetic applications were also studied.

引用

页码：355 / 364

页数：10

共 50 条

[31] PHOTOCHEMICAL-REACTIONS OF TRANSITION-METAL ORGANYL COMPLEXES WITH OLEFINS, VI[1] - REACTIONS OF TRICARBONYL (ETA-5-2,4-CYCLOHEXADIENYL)MANGANESE WITH CONJUGATED DIENES
KREITER, CG
LEHR, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (10): : 1377 - 1383
[32] REACTIONS OF COORDINATED ARENES - SYNTHESES OF SUBSTITUTED (ETA-5-CYCLOHEXADIENYL) (ETA-5-CYCLOPENTADIENYL)IRON(II), AND (ETA-6-ARENE) (ETA-4-CYCLOHEXADIENE)IRON(0) COMPLEXES
BEARD, LK
SILVON, MP
SKELL, PS
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 209 (02) : 245 - 253
[33] PREPARATION OF ENDO-6-ACETOXY AND ENDO-6-HYDROXY DERIVATIVES OF ETA5-(1,3-CYCLOHEXADIENYL)IRON TRICARBONYL FLUOROBORATE
ASHWORTH, RW
BERCHTOLD, GA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) : 5200 - 5201
[34] REACTIONS OF COORDINATED LIGANDS .5. ADDITION OF TETRAFLUOROETHYLENE TO TRICARBONYL(DIENE)IRON, TRICARBONYL(TRANS-CINNAMALDEHYDE)IRON, AND TRICARBONYL(ORTHO-STYRYLDIPHENYLPHOSPHINE)IRON COMPLEXES
BOND, A
LEWIS, B
GREEN, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (12): : 1109 - 1118
[35] Demetallation of 1,3-diene products obtained from addition of natural products to tricarbonyl(cyclohexadienyl)iron tetrafluoroborate
Odiaka, Timothy I.
Adebesin, Tunmise T.
Oladosu, Ibrahim A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 761 : 179 - 189
[36] FORMATION OF (6-ALKYLIDENE-ETA-5-CYCLOHEXADIENYL)IRON COMPLEXES BY RHODIUM-CATALYZED CARBENOID REACTIONS
MOTALLEBI, S
MULLER, P
ORGANOMETALLICS, 1993, 12 (11) : 4668 - 4672
[37] PREPARATION AND PHOTOCHEMISTRY OF METAL-METAL BONDED HETERODINUCLEAR PRECURSORS TO TETRACARBONYLCOBALT(O), TRICARBONYL ETA-5-CYCLOPENTADIENYL) MOLYBDENUM(I), TRICARBONYL, "ETA-5-CYCLOPENTADIENYL)TUNGSTEN(I), AND DICARBONYL ETA-5-CYCLOPENTADIENYL(IRON(I)
ABRAHAMSON, HB
WRIGHTON, MS
INORGANIC CHEMISTRY, 1978, 17 (04) : 1003 - 1008
[38] SYNTHESIS AND REACTIVITY OF (TRICARBONYL)-(ETA-5-2-METHYLPENTADIENYL)IRON(+ 1) CATION
DONALDSON, WA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (02) : 187 - 193
[39] HIGHLY STEREOSELECTIVE 1,4-ADDITION REACTIONS OF ALKYLIDENE MALONATE SUBSTITUTED ETA(4),(1,3-BUTADIENYL)IRON(TRICARBONYL) COMPLEXES
WADA, CK
ROUSH, WR
TETRAHEDRON LETTERS, 1994, 35 (40) : 7351 - 7354
[40] NUCLEOPHILIC-ADDITION OF CHROMIUM CARBENE ANIONS TO THE COORDINATED OLEFIN IN [CP(CO)2FE(ETA-2-OLEFIN)]+ COMPLEXES AND TO THE CYCLOHEXADIENYL LIGAND IN [(ETA-5-CYCLOHEXADIENYL)(CO)3FE]
KELLEY, C
TERRY, MR
KAPLAN, AW
GEOFFROY, GL
LUGAN, N
MATHIEU, R
HAGGERTY, BS
RHEINGOLD, AL
INORGANICA CHIMICA ACTA, 1992, 198 : 601 - 611

← 1 2 3 4 5 →