Nitrenium ions.: Part 4.: Reactivity and crystal structure of 1-methyl-2-phenyl-3-N-benzoyloxyindole iminium perchlorate and reactivity of N,N-dimethylamino-p-N-benzoyloxyaniline nitrenium chloride with 2-phenylindole

被引：9

作者：

Greci, L

Rossetti, M

Galeazzi, R

Stipa, P

Sgarabotto, P

Cozzini, P

机构：

[1] Univ Ancona, Dipartimento Sci Mat & Terra, I-60131 Ancona, Italy

[2] Univ Parma, CNR, Dipartimento Chim Gen, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 12期

关键词：

D O I：

10.1039/a805727c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Methyl-2-phenyl-3-nitrosoindole and N,N-dimethyl-p-nitrosoaniline react with benzoyl chloride to form salts behaving like iminium and nitrenium ions respectively. The structure of che ion formed in the case of the nitrosoindole was elucidated by X-ray analysis. The charge density distribution of both ions was calculated on the basis of the structure parameters and by AM1 calculations and their reactivity was interpreted on the basis of structural parameters and the calculated distribution of their positive charge.

引用

页码：2683 / 2687

页数：5

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