catena-Poly[[tribenzyltin(IV)]-μ-(E)-3-phenylprop-2-enoato-κ2O:O′]

被引：1
|
作者：
Lo, Kong Mun [1 ]
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811017247
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The SnIV atom in the title carboxylate-bridged polymer, [Sn(C7H7)(3)(C9H7O2)] (n) , exists in a trans-C3SnO2 trigonal-bipyramidal geometry (average covalent Sn-O = 2.167 A, average dative Sn-O = 2.361 A and average O-Sn-O = 169.6 degrees). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.
引用
收藏
页码：M744 / U984
页数：28
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