catena-Poly[[triphenyltin(IV)]-μ-3-methylphenylseleninato-κ2O:O′]

被引：2
|
作者：
Ru, Jing [1 ]
Zhang, Rufen [1 ]
机构：
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 14.5; mean σ(C-C) = 0.009 Å; R factor = 0.038; single-crystal X-ray study; T = 298 K; wR factor = 0.097;
D O I：
10.1107/S1600536811049245
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the polymeric title coordination compound, [Sn(C6H5)(3)(C7H7O2Se)](n), the Sn-IV atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intrachain C-H center dot center dot center dot O hydrogen bond is observed.
引用
收藏
页码：M1809 / U569
页数：11
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