Effect of gold nanoparticles on transmittance and conductance of graphene oxide thin films and efficiency of perovskite solar cells

被引:24
|
作者
Jawad, Muhammad [1 ]
Khan, Abdul Faheem [2 ]
Waseem, Amir [3 ]
Kamboh, Afzal Hussain [4 ]
Mohsin, Muhammad [1 ]
Shahzad, Sohail Anjum [1 ]
Shah, Sajid Hussain [5 ]
Mathur, Sanjay [6 ]
Shaikh, Ahson Jabbar [1 ,6 ]
机构
[1] COMSATS Univ Islamabad, Dept Chem, Abbottabad Campus, Abbottabad 22060, Pakistan
[2] Inst Space Technol, Dept Mat Sci & Engn, Islamabad 44000, Pakistan
[3] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[4] Pakistan Council Renewable Energy Technol, Islamabad 44000, Pakistan
[5] COMSATS Univ Islamabad, Dept Environm Sci, Abbottabad Campus, Abbottabad 22060, Pakistan
[6] Univ Cologne, Inst Inorgan Chem, D-50939 Cologne, Germany
关键词
Graphene oxide; AuNPs; Thin films; Perovskite solar cells; Hole transport layer; Electron transport layer; HOLE TRANSPORT LAYER; AU NANOPARTICLES; HIGHLY EFFICIENT; SIZE; PERFORMANCE; DERIVATIVES; AG;
D O I
10.1007/s13204-019-01134-x
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structural and optoelectronic properties of graphene oxide (GO) bulk material were studied, and conductance and transmittance of GO thin films in absence and presence of AuNPs were optimized for further applications. GO with 0.25 mg/mL and AuNPs (0.5 mL) on GO thin films (0.25 mg/mL) were observed to have highest transmittance of 75% and 72%, respectively, and highest conductance of 7.9x10(3) S and 8.2x10(3) S, respectively. Further, these thin films were utilized as a hole transport layer (HTL) for a prototype inverted perovskite solar cell structure. GO and AuNPs/GO deposited on FTO glass show efficiency of 1.35% and 1.25%, respectively. This decrease in efficiency is associated with the deteriorated crystalline structure of perovskite in the presence of AuNPs and similar HOMO level of AuNPs as of GO, which competes hole transfer.
引用
收藏
页码:485 / 497
页数:13
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