Solubility of Carbon Dioxide in Aqueous Blends of 2-Amino-2-methyl-1-propanol and N-Methyldiethanolamine

被引:30
|
作者
Shokouhi, Mohammad [1 ]
Zoghi, Ali Taghi [1 ]
Vahidi, Mehdi [1 ]
Moshtari, Behnoosh [1 ]
机构
[1] NIOC, RIPI, Gas Refining Technol Grp, Gas Res Div, Tehran 1485733111, Iran
来源
关键词
HYDROGEN-SULFIDE; EQUILIBRIUM SOLUBILITY; CO2; MONOETHANOLAMINE; ABSORPTION; PRESSURES; VISCOSITY; MIXTURES; REMOVAL; DENSITY;
D O I
10.1021/je500860v
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility of CO2 in aqueous solution of 40 mass % MDEA + 5 mass % AMP, 22.5 mass % MDEA + 22.5 mass % AMP, and 10 mass % MDEA + 35 mass % AMP at (313.15, 333.15, and 353.15) K and pressure from vapor pressure of solutions up to 2.5 MPa using isochoric saturation method (or volumetric-gravimetric method) were measured. The results showed that the CO2 solubility decreases with increasing of temperature and increases with rising of partial pressure of CO2 and also AMP concentration can improve absorption capacity of MDEA aqueous solution as [AMP](0)/[MDEA](0) increases. Deshmukh-Mather model and Peng-Robinson equation of state were used for liquid and vapor phase, respectively, to correlate solubility data.
引用
收藏
页码:1250 / 1258
页数:9
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