Kinetic regularities of the synthesis of soluble polyimide by termal imidization of polyamic acid in solution

被引：5
|
作者：
Ustimov, A. V. [1 ]
Tsegelskaya, A. Yu. [1 ]
Semenova, G. K. [1 ]
Kuznetsov, A. A. [1 ]
机构：
[1] Russian Acad Sci, NS Enikolopov Inst synthet polymer Mat, 70 ul Profsoyuznaya, Moscow 117393, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 06期
关键词：
Polyamic acid; imidization; kinetics; polyimide; polycondensation; CYCLIZATION; MECHANISM;
D O I：
10.1007/s11172-022-3532-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetic regularities of the synthesis of soluble polyimide by cyclization of polyamic acid in solution are investigated. The effective rate constants for the reactions of decomposition and imidization of polyamic acid occurring during imidization are determined depending on temperature. It is demonstrated that the negative deviation of the kinetics of the imidization of polyamic acid in solution from the first-order reaction equation is basically due to the influence of the polyamic acid decomposition with the formation of terminal amino groups.
引用
下载
收藏
页码：1284 / 1289
页数：6
相关论文
共 50 条
  • [31] Structure and properties of polyimide fiber prepared from polyamic acid solution with high solid content and low viscosity
    Lin, Daolei
    Jiang, Ming
    Li, Runyue
    Qi, Shengli
    Wu, Dezhen
    MATERIALS LETTERS, 2022, 312
  • [32] A new dip-coating approach for plasticization-resistant polyimide hollow fiber membranes: In situ thermal imidization and cross-linking of polyamic acid
    Yu, Hyun Jung
    An, Heseong
    Shin, Ju Ho
    Brunetti, Adele
    Lee, Jong Suk
    CHEMICAL ENGINEERING JOURNAL, 2023, 473
  • [33] Kinetic Study of Low-Temperature Imidization of Poly(amic acid)s and Preparation of Colorless, Transparent Polyimide Films
    Yu, Hwan-Chul
    Jung, Jae-Woo
    Choi, Ju-Young
    Chung, Chan-Moon
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2016, 54 (11) : 1593 - 1602
  • [34] Synthesis of soluble polyimide derived from novel naphthalene diamines for liquid crystal alignment layers and a preliminary study on the mechanism of imidization
    Xia, Senlin
    Sun, Zhen
    Yi, Longfei
    Wang, Yinghan
    RSC ADVANCES, 2013, 3 (34) : 14661 - 14670
  • [35] Synthesis and characterization of diaminophenylindane based polyimides via ester-acid solution imidization
    Farr, IV
    Glass, TE
    Ji, Q
    McGrath, JE
    HIGH PERFORMANCE POLYMERS, 1997, 9 (03) : 345 - 352
  • [36] Synthesis and properties of silica-polyimide hybrid films derived from colloidal silica particles and polyamic acid
    Shang, Zhenping
    Lue, Changli
    Lue, Xiaodan
    Gao, Lianxun
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (06) : 3477 - 3483
  • [37] SYNTHESIS OF SOLUBLE POLYIMIDES AND FUNCTIONALIZED IMIDE OLIGOMERS VIA SOLUTION IMIDIZATION OF AROMATIC DIESTER DIACIDS AND AROMATIC DIAMINES
    MOY, TM
    DEPORTER, CD
    MCGRATH, JE
    POLYMER, 1993, 34 (04) : 819 - 824
  • [38] Electrical conduction of polyimide films prepared from polyamic acid (PAA) and pre-imidized polyimide (PI) solution (Retraction of vol 1, pg 427, 2007)
    Kim, T. Y.
    Kim, W. J.
    Lee, T. H.
    Kim, J. E.
    Yoon, H. G.
    Suh, K. S.
    E-POLYMERS, 2012,
  • [39] SYNTHESIS OF SOLUBLE POLYIMIDES AND FUNCTIONALIZED IMIDE OLIGOMERS VIA SOLUTION IMIDIZATION OF AROMATIC DIESTER-DIACIDS AND AROMATIC DIAMINES
    MOY, TM
    DEPORTER, CD
    MCGRATH, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 380 - POLY
  • [40] Preparation of Polyimide-TiO2 Hybrid Films by Synthesis of Polyamic Acid Having Carboxylic Acid Group Sidechains in the Presence of TiO2
    Hodozuka, Yuuki
    Morikawa, Atsushi
    JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2023, 36 (05) : 299 - 304
12345