Homochirality of biomolecules: Counter-arguments against critical notes

被引:15
|
作者
Keszthelyi, L [1 ]
机构
[1] Biol Res Ctr, Inst Biophys, H-6701 Szeged, Hungary
来源
ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES | 2001年 / 31卷 / 03期
基金
匈牙利科学研究基金会; 美国国家科学基金会;
关键词
circularly polarized light; enantiomers; magnetochiral; parity-violating energy difference; photochemistry; synchrotron radiation;
D O I
10.1023/A:1010758205545
中图分类号
Q [生物科学];
学科分类号
07 ; 0710 ; 09 ;
摘要
Three recently published critical papers by Bonner and coworkers on the extraterrestrial origin of the homochirality of biomolecules and the amplification of tiny enantiomeric excess are discussed. The presented arguments show the difficulties involved in circularly polarized u.v. and visible synchrotron radiation from neutron stars, in their ratio to non circularly polarized light and in racemization of the products. Attention is called upon another mechanism for production of extraterrestrial handedness based on Salam's condensation theory and on the recent experimental demonstration of the enantioselective magnetochiral photochemistry. Arguments, as well as experiments, point out that tiny enantiomeric excesses might be amplified via the Yamagata accumulation principle questioned by Bonner.
引用
收藏
页码:249 / 256
页数:8
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