Ba2[WO3F(IO3)][WO3F2]: the first polar fluorinated tungsten iodate featuring a direct W-O-I bond

被引：3

作者：

Hou, Ying ^{[1
]}

Li, Hongyi ^{[2
]}

Wu, Hongping ^{[1
]}

Yu, Hongwei ^{[1
]}

Hu, Zhanggui ^{[1
]}

Wang, Jiyang ^{[1
]}

Wu, Yicheng ^{[1
]}

机构：

[1] Tianjin Univ Technol, Inst Funct Crystal, Tianjin Key Lab Funct Crystal Mat, Tianjin 300384, Peoples R China

[2] Guangzhou Panyu Polytech, Guangzhou 511483, Guangdong, Peoples R China

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 37期

基金：

中国国家自然科学基金;

关键词：

NONLINEAR-OPTICAL MATERIAL; CRYSTAL; CATIONS; OXIDE;

D O I：

10.1039/d2dt02085h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The introduction of the transition metal cations with d(0) electron configurations and F in the iodate systems generates a new polar compound, Ba-2[WO3F(IO3)][WO3F2], which features the first example of a direct W-O-I bond in the structure. It exhibits excellent properties, including a large second harmonic generation response (similar to 3.5 x KH2PO4), a wide visible and mid-infrared transparency region (0.28-10.74 mu m), and a moderate birefringence of 0.061@532 nm.

引用

页码：14036 / 14040

页数：5

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