N-[2-(4-hydroxybenzylideneamino)ethyl]-N-[2-(4-oxidobenzylideneamino)ethyl]ammonium

被引：0
|
作者：
Tian, Xiu-Mei [1 ]
Liu, Gang [1 ]
Feng, Yue [1 ]
Wang, Ji-De [1 ]
机构：
[1] Xinjiang Univ, Sch Chem & Chem Engn, Urumqi 830046, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807037397
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title Schiff base compound, C18H21N3O2, was synthesized by a condensation reaction of 4-hydroxybenzaldehyde with diethylenetriamine. The crystal structure determination reveals that one of the terminal hydroxy groups is deprotonated while the imino group of the molecule is protonated; thus the compound is a zwitterion. The two terminal benzene rings are nearly parallel to one another, with a dihedral angle of 9.94 (6)degrees. Intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonding helps to stabilize the crystal structure.
引用
收藏
页码：O3701 / U2061
页数：9
相关论文
共 50 条
  • [41] 4,5-Dihydroxyimidazolidin-2-ones in an α-ureidoalkylation reaction of N-(carboxyalkyl)-, N-(hydroxyalkyl)-, and N-(aminoalkyl)ureas 3. α-Ureidoalkylation of N-[2-(dimethylamino)ethyl]urea
    Gazieva, G. A.
    Lozhkin, P. V.
    Baranov, V. V.
    Nelyubina, Yu. V.
    Kravchenko, A. N.
    Makhova, N. N.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (12) : 2488 - 2493
  • [42] N-{2-[4-(2-Hydroxyethyl)piperazin-1-yl]ethyl}phthalimide
    Shao, Ying
    An, Dong
    Zhou, Mi
    Liu, Li
    Sun, Xiao-Qiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68
  • [43] 4,5-Dihydroxyimidazolidin-2-ones in an α-ureidoalkylation reaction of N-(carboxyalkyl)-, N-(hydroxyalkyl)-, and N-(aminoalkyl)ureas 3. α-Ureidoalkylation of N-[2-(dimethylamino)ethyl]urea
    G. A. Gazieva
    P. V. Lozhkin
    V. V. Baranov
    Yu. V. Nelyubina
    A. N. Kravchenko
    N. N. Makhova
    Russian Chemical Bulletin, 2009, 58 : 2488 - 2493
  • [44] Synthesis, crystal structures and characterization of three novel complexes with N-[2-(2-hydroxybenzylideneamino)ethyl]-4-methyl-benzene-sulfonamide as ligand
    Li, Shu-Ni
    Zhai, Quan-Guo
    Hu, Man-Cheng
    Jiang, Yu-Cheng
    INORGANICA CHIMICA ACTA, 2009, 362 (07) : 2217 - 2221
  • [45] Bis{μ-N-[(2-(dimethylamino)ethyl]-N′-(trimethylsilyl)benzamidinato}dilithium(I)
    Tong, HB
    Wei, XH
    Liu, DS
    Huang, SP
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M825 - M826
  • [46] [N-((E)-2-{[2-(Dimethylamino)ethyl]iminomethyl}phenyl)-N-(2,6-dimethylphenyl)anilinido-κ3N,N′,N"]ethylzinc
    Issa-Madongo, Mathurin
    Mu, Ying
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M364 - U770
  • [47] Crystal structure and antitumor activity of tri[2-[N-(4′-methylbenzylsulfonyl)amino]ethyl]-amine
    Tai, XS
    Yin, MH
    Tan, MY
    Li, YZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (04) : 411 - 414
  • [48] STRUCTURE OF CHLORO(N-[2-(4-IMIDAZOLYL)ETHYL]SALICYLIDENEAMINATO)COPPER(II) MONOHYDRATE
    LATOUR, JM
    TANDON, SS
    LEONARD, GA
    POVEY, DC
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 598 - 600
  • [49] N-[2-(3,4-Dimethoxyphenyl)ethyl]-N-methylbenzenesulfonamide
    Vennila, Jasmine P.
    Thiruvadigal, D. John
    Kamala, E. Theboral Sugi
    Kavitha, Helen P.
    Manivannan, V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O882 - U3258
  • [50] N-{2-[N-(4-Methylphenyl)oxamoyl]phenyl}propanamide
    Pervez, Humayun
    Ahmad, Maqbool
    Yaqub, Muhammad
    Tahir, M. Nawaz
    Saira, Naveeda
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1729 - U787
12345