Efficient palladium-catalysed enamide synthesis from enol triflates and enol tosylates

被引：54
|
作者：
Willis, MC [1 ]
Brace, GN
Holmes, IP
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] GlaxoSmithKline Inc, Med Res Ctr, Discovery Res, Stevenage SG1 2NY, Herts, England
来源：
SYNTHESIS-STUTTGART | 2005年 / 19期
关键词：
enamides; palladium; catalysis; enol triflates; enol tosylates;
D O I：
10.1055/s-2005-918480
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalysts generated from Pd-2(dba)(3) and biphenyl ligands 4 and 7 efficiently promote the coupling of amides and carbamates With unactivated vinyl triflates and tosylates, to provide enamides in food to excellent yields.
引用
收藏
页码：3229 / 3234
页数：6
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