Concise asymmetric synthesis of the sex pheromone of the tea tussock moth

被引:12
|
作者
Sun, Zhi-Feng [1 ,2 ]
Zhou, Lu-Nan [1 ]
Meng, Yifei [1 ]
Zhang, Tao [1 ]
Du, Zhen-Ting [1 ]
Zheng, Huaiji [1 ]
机构
[1] North West Agr & Forestry Univ, Coll Chem & Pharm, Shaanxi Key Lab Nat Prod & Chem Biol, Yangling 712100, Shaanxi, Peoples R China
[2] Shaanxi Univ Technol, Coll Chem & Environm Sci, Shaanxi Key Lab Catalysis, Hanzhong 723001, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
EUPROCTIS-PSEUDOCONSPERSA STRAND; JULIA OLEFINATION; LYMANTRIIDAE; LEPIDOPTERA; ISOBUTYRATE; RESPONSES; PRODUCT;
D O I
10.1016/j.tetasy.2017.09.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A concise asymmetric total synthesis of the sex pheromone of the tea tussock moth has been achieved from commercially available starting materials. The chiral moiety was introduced by Evans' template and the key C-C bond construction was accomplished through Julia-Kocienski coupling and Wittig olefination. The salient characteristic of our synthetic route is that it is protecting a group free. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1562 / 1567
页数:6
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