Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation

被引：15
|
作者：
Zhuo, Chao [1 ]
Wang, Fei [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 39期
关键词：
METAL-ORGANIC FRAMEWORKS; CAPTURE PROPERTIES; CRYSTAL-STRUCTURES; PORE OPENINGS; AMINO-ACID; DESIGN; RECOGNITION; TOPOLOGIES; ZMOFS; CAGES;
D O I：
10.1039/c8ce00403j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A pair of homochiral zeolitic imidazolate framework (S(R)-ZIF-78h) materials of GME topology possessing enantiopure benzimidazolate (S(R)-OH-bim) linkers have been synthesized via solvent-assisted linker exchange (SALE) of ZIF-78, which has been confirmed through H-1 NMR, elemental analysis, powder X-ray diffraction, gas adsorption and circular dichroism (CD). Remarkably, the representative S-ZIF-78h material exhibits permanent porosity and enantioselective sensing and separation ability towards proline.
引用
收藏
页码：5925 / 5928
页数：4
相关论文
共 50 条
  • [41] Solvent-assisted linker exchange (SALE) and post-assembly metallation in porphyrinic metal-organic framework materials
    Takaishi, Shinya
    DeMarco, Erica J.
    Pellin, Michael J.
    Farha, Omar K.
    Hupp, Joseph T.
    CHEMICAL SCIENCE, 2013, 4 (04) : 1509 - 1513
  • [42] Solvent-assisted linker exchange: A strategy for obtaining desirable, but previously synthetically inaccessible, metal-organic framework materials
    Hupp, Joseph
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [43] Synthesis of nano zinc-based metal-organic frameworks under ultrasound irradiation in comparison with solvent-assisted linker exchange: Increased storage of N2 and CO2
    Abbasi, Amir Reza
    Moshtkob, Ayda
    Shahabadi, Nahid
    Masoomi, Mohammad Yaser
    Morsali, Ali
    ULTRASONICS SONOCHEMISTRY, 2019, 59
  • [44] In Situ Thermal Solvent-Free Synthesis of Zeolitic Imidazolate Frameworks with High Crystallinity and Porosity for Effective Adsorption and Catalytic Applications
    Wang, Jichao
    Chaemchuen, Somboon
    Klomkliang, Nikom
    Verpoort, Francis
    CRYSTAL GROWTH & DESIGN, 2021, 21 (09) : 5349 - 5359
  • [45] Surface wettability switching of a zeolitic imidazolate framework mesh via surface ligand exchange for oil-water separation
    Du, Xinxin
    Fan, Lili
    Zhang, Minghui
    Kang, Zixi
    Fan, Weidong
    Wen, Meilian
    Zhang, Yuming
    Li, Mengfei
    Wang, Rongming
    Sun, Daofeng
    MATERIALS RESEARCH BULLETIN, 2019, 111 : 301 - 305
  • [46] Direct Recycling of Ternary Lithium-Ion Batteries via Solvent-Assisted Separation of Cathode Materials
    Gong, Cheng
    Zhang, Shiwen
    Bi, Wentuan
    INORGANIC CHEMISTRY, 2025, 64 (12) : 6286 - 6292
  • [47] Data-driven parameter optimization for the synthesis of high-quality zeolitic imidazolate frameworks via a microdroplet route
    He, Xiang
    Chen, Jianping
    Albin, Shane
    Zhu, Zan
    Wang, Wei-Ning
    ADVANCED POWDER TECHNOLOGY, 2021, 32 (01) : 266 - 271
  • [48] Fast-Response Low Humidity Sensor Based on on Ionic Liquid Functionalized MOF-801 by Solvent-Assisted Linker Exchange
    Wu, Ke
    Miao, Xiaoya
    Ma, Zhiyan
    Hou, Zhaonan
    Yu, Yunlong
    Guan, Xin
    Zhao, Hongran
    Liu, Sen
    Fei, Teng
    Zhang, Tong
    IEEE ELECTRON DEVICE LETTERS, 2022, 43 (11) : 1969 - 1972
  • [49] Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation
    Deria, Pravas
    Chung, Yongchul G.
    Snurr, Randall Q.
    Hupp, Joseph T.
    Farha, Omar K.
    CHEMICAL SCIENCE, 2015, 6 (09) : 5172 - 5176
  • [50] Functionalized Defects through Solvent-Assisted Linker Exchange: Synthesis, Characterization, and Partial Postsynthesis Elaboration of a Metal-Organic Framework Containing Free Carboxylic Acid Moieties
    Karagiaridi, Olga
    Vermeulen, Nicolaas A.
    Klet, Rachel C.
    Wang, Timothy C.
    Moghadam, Peyman Z.
    Al-Juaid, Salih S.
    Stoddart, J. Fraser.
    Hupp, Joseph T.
    Farha, Omar K.
    INORGANIC CHEMISTRY, 2015, 54 (04) : 1785 - 1790
12345