New developments in nuclear magnetic resonance using noise spectroscopy

被引:20
|
作者
Yang, DK [1 ]
Atkins, JE [1 ]
Lester, CC [1 ]
Zax, DB [1 ]
机构
[1] Cornell Univ, Dept Chem, Baker Lab, Ithaca, NY 14853 USA
关键词
D O I
10.1080/002689798166387
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the 30 years since Ernst and Kaiser introduced the idea of incoherent radiation fields and their application to NMR spectroscopy, relatively few researchers have exploited the advantages of noise spectroscopy. Some recent applications of one-dimensional noise spectroscopy in NMR are presented which display a versatility which commonly is not appreciated. Excitation schemes are discussed which demonstrate both broadband and narrowband features, and demonstrate both theoretically and experimentally how noise spectroscopy allows for the observation of distortion-free broadline spectra in solids which may not be amenable to techniques more traditionally used in pulsed NMR experiments. It is argued that these applications of noise spectroscopy deserve a more common place in the experimentalist's arsenal.
引用
收藏
页码:747 / 757
页数:11
相关论文
共 50 条