[Cu12(P2Se6){Se2P(OR)2}8]:: Discrete copper clusters containing an ethane-like hexaselenodiphosphate(IV)

被引：0

作者：

Liu, CW ^{[1
]}

Chen, HC

Wang, JC

Keng, TC

机构：

[1] Chung Yuan Christian Univ, Dept Chem, Chungli 320, Taiwan

[2] Soochow Univ, Dept Chem, Taipei 111, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 12期

关键词：

cluster compounds; coordination modes; copper; phosphorus; selenium;

D O I：

10.1002/1521-3773(20010618)40:12<2342::AID-ANIE2342>3.0.CO;2-H

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coexistence of P4+ and P5+ in one complex and the presence of an ethane-like hexaselenodiphosphato ligand, P2Se64-, are the novel features of the title compounds (see structure, in which R = Et or iPr; OR groups omitted for clarity). The coordination mode of P2Se64- in these dodecanuclear copper species is unprecedented and has not even been identified in any mixed ligands containing Group 15/16 elements.

引用

页码：2342 / +

页数：4

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