catena-Poly[bis(propane-1,3-diaminium) [[aqua(sulfato-κO)bis(sulfato-κ2 O,O′)cerate(IV)]-μ-sulfato-κ3 O,O′:O"] dihydrate]

被引：0
|
作者：
Meer, Ali Farooq [2 ]
Ahmad, Saeed [2 ]
Sharif, Shahzad [3 ]
Khan, Islam Ullah [3 ]
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Univ Engn & Technol, Dept Chem, Lahore 54890, Pakistan
[3] Govt Coll Univ, Dept Chem, Mat Chem Lab, Lahore 54000, Pakistan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811008324
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The CeIV atom in the title salt, {(H3NCH2CH2CH2NH3)(2)[Ce(SO4)(4)(H2O)]center dot 2H(2)O} (n) , exists in a monocapped square-antiprismatic coordination geometry. The water-coordinated metal atom is bonded to four sulfate ions; one of them is monodentate and two function in a chelating mode. The fourth is also chelating but it uses one of the other two O atoms to bind to an adjacent metal atom, generating a polyanionic chain. The cations are linked to the polyanionic chain as well as to the uncoordinated water molecules, resulting in an O-H...O and N-H...O hydrogen-bonded three-dimensional network.
引用
收藏
页码：M413 / U312
页数：12
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