catena-Poly[[triaqua(pyridine-κN)nickel(II)]-μ-sulfato-κ2O:O′]

被引：2
|
作者：
Shi, Yan-Fang [1 ]
Li, Fu-Xing [1 ]
Geng, Bo [1 ]
Liu, Yan-Cheng [1 ]
Chen, Zhen-Feng [1 ]
机构：
[1] Guangxi Normal Univ, Sch Chem & Chem Engn, Minist Educ China, Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1107/S1600536809049605
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ni(SO4)(C5H5N)(H2O)(3)](n), was synthesized by the hydrothermal reaction of NiSO4 center dot 6H(2)O, pyridine and water. The central Ni-II atom is coordinated in a distorted octahedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C-H group.
引用
收藏
页码：M1665 / U1437
页数：11
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