Highly selective methanesulfonic acid-catalyzed 1,3-isomerization of allylic alcohols

被引：29
|
作者：
Leleti, Rajender Reddy [1 ]
Bin Hu [1 ]
Prashad, Mahavir [1 ]
Repic, Jan [1 ]
机构：
[1] Novartis Pharmaceut Corp, Chem & Analyt Dev, Process R&D, E Hanover, NJ 07936 USA
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 48期
关键词：
methanesulfonic acid; allylic alcohols; 1,3-isomerization; THF; water;
D O I：
10.1016/j.tetlet.2007.09.156
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Secondary and tertiary allylic alcohols undergo 1,3-isomerization smoothly in the presence of methanesulfonic acid under simple and efficient conditions to afford selectively the corresponding primary E-allylic alcohols in excellent yields. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8505 / 8507
页数：3
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