Hierarchitecture Co2(OH)3Cl@FeCo2O4 composite as a novel and high-performance electrode material applied in supercapacitor

被引:11
|
作者
Wang, Zidong [1 ]
Hong, Ping [1 ]
Peng, Sijia [1 ]
Zhang, Xu [1 ]
Zou, Tong [1 ]
Yang, Yue [2 ]
Zhao, Rongjun [1 ]
Wang, Yude [1 ,3 ]
机构
[1] Yunnan Univ, Sch Mat Sci & Engn, Kunming, Yunnan, Peoples R China
[2] Yunnan Univ, Dept Phys, Kunming, Yunnan, Peoples R China
[3] Yunnan Univ, Key Lab Quantum Informat Yunnan Prov, Kunming, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
Co-2(OH)(3)Cl@FeCo2O4; supercapacitors; electrochemical performances; one-step hydrothermal synthesis; INTERCONNECTED MESOPOROUS STRUCTURES; BINDER-FREE ELECTRODES; LITHIUM-ION BATTERY; ELECTROCHEMICAL PERFORMANCES; ASYMMETRIC SUPERCAPACITORS; COBALT HYDROXIDE; ENERGY-STORAGE; ANODE MATERIAL; NICO2O4; CARBON;
D O I
10.1002/er.5152
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
One-step hydrothermal reaction has successfully been used to prepared three-dimensional hierarchitecture Co-2(OH)(3)Cl@FeCo2O4 composite without any annealing treatment. The samples are investigated to confirm the crystal structure, elemental composition, morphology structure and electrochemical performance. The results show the sample has a three-dimensional hierarchitecture that nanoblocks are assembled with nanoparticles. And the specific surface area is 87.5 m(2) g(-1) and the total pore volume is 0.17 cm(3) g(-1). Meanwhile, the composite shows a high specific capacitance of 1110.0 F center dot g(-1) at 1 A center dot g(-1) and great cycling stability with 98.8% capacitance retention after 3000 cycles. To evaluate the electrochemical performances, the results are used to compare with the Co-2(OH)(3)Cl and FeCo2O4 nanomaterials, indicating a higher capacitance and longer cycle stability shown by the as-synthesized sample. The as-synthesized Co-2(OH)(3)Cl@FeCo2O4 composite has an outstanding electrochemical performance, predicting an enormous potential and promising future as a novel electrode material applied in supercapacitor.
引用
收藏
页码:3122 / 3133
页数:12
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