Phenanthroline-fused unsymmetrical phthalocyanines chelating rhenium(I) tricarbonyl units: Synthesis, spectroscopy and electrochemical properties

被引：2
|
作者：
Lin, Chenxiang [1 ]
Yang, Jian [1 ,2 ,3 ]
Li, Senzhi [1 ]
Gong, Lei [1 ]
Gao, Ying [1 ]
Chen, Yuxiang [1 ]
Che, Ping [1 ]
Qi, Dongdong [1 ]
Li, Jianfeng [2 ,3 ]
Bian, Yongzhong [1 ,4 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China
[2] Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, CAS Ctr Excellence Topol Quantum Computat, Beijing 101408, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 101408, Peoples R China
[4] Univ Sci & Technol Beijing, Daxing Res Inst, Beijing 100083, Peoples R China
来源：
DYES AND PIGMENTS | 2021年 / 195卷
基金：
北京市自然科学基金; 中国国家自然科学基金;
关键词：
Phthalocyanine; Rhenium; Phenanthroline; Single crystal X-ray diffraction analysis; Electrochemistry; Fluorescence lifetime; NONLINEAR-OPTICAL PROPERTIES; METAL-FREE; SILICON PHTHALOCYANINES; ELECTRONIC-STRUCTURE; ZINC PORPHYRIN; REDUCTION; CO2; METALLOPHTHALOCYANINES; PHOTOCATALYSTS; PHOTOREDUCTION;
D O I：
10.1016/j.dyepig.2021.109716
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Phenanthroline-fused unsymmetrical phthalocyanine (2-H) and its zinc complex (2-Zn) were treated with Re (CO)(5)Cl to give rhenium(I) tricarbonyl chloride chelates 1-H and 1-Zn respectively, which represent the first example of phthalocyanines with peripherally appended rhenium(I) complex units. The molecular structure of 1-Zn was determined by single crystal X-ray diffraction analysis. The electronic absorption, magnetic circular dichroism, and steady-state and time-resolved fluorescence spectra and the singlet oxygen (O-1(2)) generation efficiencies of 1-H and 1-Zn were measured and compared with those of phenanthroline-fused unsymmetrical phthalocyanines 2-H and 2-Zn, and the corresponding symmetrical phthalocyanines 3-H and 3-Zn as well. The electrochemical properties of 1-H and 1-Zn were also studied by cyclic voltammetry and compared with those of 2-H and 2-Zn. The effects of unsymmetrical phenanthroline fusing and rhenium(I) chelating on the photophysical and electrochemical behaviors of phthalocyanines were highlighted based on the above investigations.
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页数：6
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