Phenanthroline-fused unsymmetrical phthalocyanines chelating rhenium(I) tricarbonyl units: Synthesis, spectroscopy and electrochemical properties

被引：2
|
作者：
Lin, Chenxiang [1 ]
Yang, Jian [1 ,2 ,3 ]
Li, Senzhi [1 ]
Gong, Lei [1 ]
Gao, Ying [1 ]
Chen, Yuxiang [1 ]
Che, Ping [1 ]
Qi, Dongdong [1 ]
Li, Jianfeng [2 ,3 ]
Bian, Yongzhong [1 ,4 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China
[2] Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, CAS Ctr Excellence Topol Quantum Computat, Beijing 101408, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 101408, Peoples R China
[4] Univ Sci & Technol Beijing, Daxing Res Inst, Beijing 100083, Peoples R China
来源：
DYES AND PIGMENTS | 2021年 / 195卷
基金：
北京市自然科学基金; 中国国家自然科学基金;
关键词：
Phthalocyanine; Rhenium; Phenanthroline; Single crystal X-ray diffraction analysis; Electrochemistry; Fluorescence lifetime; NONLINEAR-OPTICAL PROPERTIES; METAL-FREE; SILICON PHTHALOCYANINES; ELECTRONIC-STRUCTURE; ZINC PORPHYRIN; REDUCTION; CO2; METALLOPHTHALOCYANINES; PHOTOCATALYSTS; PHOTOREDUCTION;
D O I：
10.1016/j.dyepig.2021.109716
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Phenanthroline-fused unsymmetrical phthalocyanine (2-H) and its zinc complex (2-Zn) were treated with Re (CO)(5)Cl to give rhenium(I) tricarbonyl chloride chelates 1-H and 1-Zn respectively, which represent the first example of phthalocyanines with peripherally appended rhenium(I) complex units. The molecular structure of 1-Zn was determined by single crystal X-ray diffraction analysis. The electronic absorption, magnetic circular dichroism, and steady-state and time-resolved fluorescence spectra and the singlet oxygen (O-1(2)) generation efficiencies of 1-H and 1-Zn were measured and compared with those of phenanthroline-fused unsymmetrical phthalocyanines 2-H and 2-Zn, and the corresponding symmetrical phthalocyanines 3-H and 3-Zn as well. The electrochemical properties of 1-H and 1-Zn were also studied by cyclic voltammetry and compared with those of 2-H and 2-Zn. The effects of unsymmetrical phenanthroline fusing and rhenium(I) chelating on the photophysical and electrochemical behaviors of phthalocyanines were highlighted based on the above investigations.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] Syntheses, Characterization, and Properties of Rhenium(I) Tricarbonyl Complexes with Tetrathiafulvalene-Fused Phenanthroline Ligands
    Qin, Jie
    Hu, Liang
    Li, Gao-Nan
    Wang, Xi-Sen
    Xu, Yan
    Zuo, Jing-Lin
    You, Xiao-Zeng
    ORGANOMETALLICS, 2011, 30 (08) : 2173 - 2179
  • [2] Ruthenium coordinated dimer of phenanthroline-fused phthalocyaninato zinc complex. Synthesis, spectroscopic, and electrochemical properties
    Kan, Jinglan
    Chen, Chao
    Wang, Kang
    Chen, Yuxiang
    Jiang, Jianzhuang
    DYES AND PIGMENTS, 2014, 105 : 63 - 65
  • [3] Synthesis, self-assembly, and semiconducting properties of phenanthroline-fused phthalocyanine derivatives
    Kan, Jinglan
    Chen, Yanli
    Gao, Jian
    Wan, Liang
    Lei, Tianjiao
    Ma, Pan
    Jiang, Jianzhuang
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (31) : 15695 - 15701
  • [4] PREPARATION AND OPTICAL AND ELECTROCHEMICAL PROPERTIES OF UNSYMMETRICAL PHTHALOCYANINES WITH ONE OR TWO TTF UNITS
    Kimura, Takeshi
    Takahashi, Nobuhiro
    Tajima, Tomoyuki
    Takaguchi, Yutaka
    HETEROCYCLES, 2012, 84 (01) : 333 - 337
  • [5] Synthesis, characterization, photophysical and electrochemical properties of fac-tricarbonyl(4,7-dichloro-1,10-phenanthroline)rhenium(I) complexes
    Goncalves, Marcia R.
    Frin, Karina P. M.
    POLYHEDRON, 2015, 97 : 112 - 117
  • [6] Synthesis, characterization, photophysical and electrochemical properties of rhenium(I) tricarbonyl diimine complexes with triphenylphosphine ligand
    Goncalves, Marcia R.
    Frin, Karina P. M.
    POLYHEDRON, 2017, 132 : 20 - 27
  • [7] α-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES WITH ONE THROUGH THREE TTF UNITS AND THEIR OPTICAL AND ELECTROCHEMICAL PROPERTIES
    Kimura, Takeshi
    Takahashi, Nobuhiro
    Tajima, Tomoyuki
    Takaguchi, Yutaka
    HETEROCYCLES, 2012, 86 (01) : 679 - 686
  • [8] Synthesis and properties of rhenium tricarbonyl complex bearing N-fused tetraphenylporphyrin ligand
    Toganoh, M
    Ishizuka, T
    Furuta, H
    CHEMICAL COMMUNICATIONS, 2004, (21) : 2464 - 2465
  • [9] Synthesis, reactivity, and properties of N-fused porphyrin rhenium(l) tricarbonyl complexes
    Toganoh, Motoki
    Ikeda, Shinya
    Furuta, Hiroyuki
    INORGANIC CHEMISTRY, 2007, 46 (23) : 10003 - 10015
  • [10] Synthesis, photophysical and electrochemical properties of novel unsymmetrical phthalocyanines with a Sudan IV moiety
    Ozcesmeci, Ibrahim
    Buyuk, Pinar
    Nar, Ilgin
    Gul, Ahmet
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2018, 22 (1-3) : 112 - 120
12345