Synthesis of carbon nanostructures by the pyrolysis of wood sawdust in a tubular reactor

被引:48
|
作者
Sebag Bernd, Maria G. [1 ]
Braganca, Saulo R. [1 ]
Heck, Nestor [1 ]
da Silva Filho, Luiz C. P. [1 ]
机构
[1] Fed Univ Rio Grande do Sul UFRGS, Postgrad Course Mines Met & Mat PPGEM, Porto Alegre, RS, Brazil
来源
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2017年 / 6卷 / 02期
关键词
Carbon nanostructures; Tubular reactor; Wood pyrolysis; Thermodynamic simulation; HYDROTHERMAL CARBONIZATION; NANOTUBES;
D O I
10.1016/j.jmrt.2016.11.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Carbon nanostructures were produced by wood sawdust pyrolysis. The results obtained revealed that the thermodynamic simulations (FactSage) were successful to predict the best reaction conditions for the synthesis of carbon, and potentially carbon fibers and nanotubes production. Graphite formation was indicated by XRD study, and by thermal analysis which presented the carbon oxidation range. The morphology of the samples (SEM/TEM analysis) showed carbon nanotubes/nanofibers varying in size and thickness, with defects and flaws. The tubular reactor was considered to be an economic and environmental correct way to nanomaterials growing, with the simultaneous generation of hydrogen and lower pollutant gas emissions.(C) 2016 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier Editora Ltda. This is an open access article under the CC BY-NC-ND license
引用
收藏
页码:171 / 177
页数:7
相关论文
共 50 条
  • [31] Macrokinetic model of pyrolysis of carbonaceous feedstock in a tubular reactor
    Bykov, V. I.
    Lomakin, S. M.
    Tsybenova, S. B.
    Varfolomeev, S. D.
    DOKLADY CHEMISTRY, 2016, 467 : 76 - 78
  • [32] PYROLYSIS CHARACTERISTICS OF CORN STALK HEMICELLULOSE IN A TUBULAR REACTOR
    Cheng Heli
    Zhan Huaiyu
    Fu Shiyu
    RESEARCH PROGRESS IN PAPER INDUSTRY AND BIOREFINERY (4TH ISETPP), VOLS 1-3, 2010, : 69 - 72
  • [33] Production of activated carbon from rubber wood sawdust
    Srinivasakannan, C
    Abu Bakar, MZ
    BIOMASS & BIOENERGY, 2004, 27 (01): : 89 - 96
  • [34] Activated Carbon from Rubber Wood Sawdust by Carbon Dioxide Activation
    Mazlan, Mohammad Amir Firdaus
    Uemura, Yoshimitsu
    Yusup, Suzana
    Elhassan, Fathelrahman
    Uddin, Azhar
    Hiwada, Ai
    Demiya, Mitsutaka
    PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 : 530 - 537
  • [35] Synthesis of beta carbon nitride nanostructures by simple CVD-pyrolysis method
    Ramasamy, Venkatesh
    Pumlianmunga
    Karuppannan, Ramesh
    DIAMOND AND RELATED MATERIALS, 2021, 111
  • [36] Synthesis of different magnetic carbon nanostructures by the pyrolysis of ferrocene at different sublimation temperatures
    Liu, Qingfeng
    Chen, Zhi-Gang
    Liu, Bilu
    Ren, Wencai
    Li, Feng
    Cong, Hongtao
    Cheng, Hui-Ming
    CARBON, 2008, 46 (14) : 1892 - 1902
  • [37] SUPERCRITICAL GAS EXTRACTION OF WOOD WITH METHANOL IN A TUBULAR REACTOR
    POIRIER, MG
    AHMED, A
    GRANDMAISON, JL
    KALIAGUINE, SCF
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1987, 26 (09) : 1738 - 1743
  • [38] Thermal behavior and kinetics of the pyrolysis of the raw/steam exploded poplar wood sawdust
    Gu, Xiaoli
    Liu, Cheng
    Jiang, Xiangjin
    Ma, Xu
    Li, Lixian
    Cheng, Kanghua
    Li, Zhongzheng
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 106 : 177 - 186
  • [39] Characterizations of Bio-char from Fast Pyrolysis of Meranti Wood Sawdust
    Mazlan, M. A. F.
    Uemura, Y.
    Osman, N. B.
    Yusup, S.
    3RD INTERNATIONAL CONFERENCE ON SCIENCE & ENGINEERING IN MATHEMATICS, CHEMISTRY AND PHYSICS 2015 (SCITECH 2015), 2015, 622
  • [40] Pyrolysis of wood sawdust: Effects of process parameters on products yield and characterization of products
    Varma, Anil Kumar
    Thakur, Lokendra Singh
    Shankar, Ravi
    Mondal, Prasenjit
    WASTE MANAGEMENT, 2019, 89 : 224 - 235