Rheology and flow during high solids emulsion polymerization of styrene

被引：20
|
作者：
Kemmere, MF [1 ]
Meuldijk, J [1 ]
Drinkenburg, AAH [1 ]
German, AL [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Chem Reactor Engn & Proc Dev, NL-5600 MB Eindhoven, Netherlands
来源：
POLYMER REACTION ENGINEERING | 1998年 / 6卷 / 3-4期
关键词：
Chemical reactors - Emulsion polymerization - Fouling - Mixing - Mixtures - Monomers - Particle size analysis - Rheology;
D O I：
10.1080/10543414.1998.10744492
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Commercial emulsion polymerization processes are often carried out with high solids (50 percent monomer by weight) recipes, resulting in relatively viscous, pseudo-plastic reaction mixtures. The change in rheological behavior during high solids emulsion polymerization complicates the process operation in terms of imperfect mixing and reactor fouling. This paper discusses the rheology and flow during high solids emulsion polymerization of styrene, as well as the effect of particle size distribution.
引用
收藏
页码：243 / 268
页数：26
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